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991.
Demin A. M. Kandarakov O. F. Minin A. S. Kuznetsov D. K. Uimin M. A. Shur V. Ya. Belyavsky A. V. Krasnov V. P. 《Russian Chemical Bulletin》2021,70(6):1199-1208
Russian Chemical Bulletin - Peculiar features of the modification of Fe3O4 magnetic nanoparticles (MNPs) obtained by co-precipitation from solutions of FeII and FeIII salts (10-nm MNPs) and by the... 相似文献
992.
K. Sai Bhavani T. Anusha J. V. Shanmukha Kumar Pradeep Kumar Brahman 《Electroanalysis》2021,33(1):97-110
Direct alcohol fuel cells (DAFCs) have been recently playing a pivotal role in electrochemical energy sources and portable electronics. Research in DAFCs has proceeded to engage major attention due to their high catalytic activity, long-term stability, portability, and low cost. Herein, we present a facile surfactant-free route to anchor bimetallic Pd−W nanoparticles supported fullerene-C60 catalyst (Pd-W@Fullerene-C60) for high-performance electrooxidation of alcohols (methanol & ethanol) for DAFCs applications. Structural, elemental composition, and morphological analysis of the proposed catalyst were carried out using UV-Vis spectroscopy, X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) and energy-dispersive x-ray spectroscopy (EDX). Electrochemical properties such as electrochemical activity, electrochemical active surface area (ECSA), and long-term stability of the Pd-W@Fullerene-C60 catalyst for ethanol and methanol oxidation in the alkaline medium were explored by using cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and chronoamperometry (CA). Results revealed that the proposed catalyst showed enlarged ECSA, tremendous electrocatalytic activity, high poison tolerance limit, good reproducibility, and enhanced long-term stability as compared to the monometallic catalyst and commercially available catalyst (Pt/C) towards ethanol and methanol oxidation reaction. This enhanced potentiality of the Pd-W@Fullerene-C60 catalyst is due to the synergistic effect of W−Pd nanoparticles and excellent electron kinetic from fullerene support material. These findings strongly suggest the Pd-W@Fullerene-C60 catalyst as potential anode material for the alcohol oxidation reaction. 相似文献
993.
Akkaraboyina Lakshmi Lavanya K. Gowri Bala Kumari K. R. S. Prasad Pradeep Kumar Brahman 《Electroanalysis》2021,33(3):591-600
In this work, an economically viable, very low cost, indigenous, ubiquitously available electrochemical sensor based on bimetallic nickel and tungsten nanoparticles modified pencil graphite electrode (NiNP-WNP@PGE) was fabricated for the sensitive and selective detection of bisphenol A (BPA). The NiNP-WNP@PGE sensor was prepared by a facile electrochemical one step co-deposition method. The prepared nanocomposite was morphologically characterized by scanning electron microscopy (SEM), energy dispersive X-ray (EDX), X-ray diffraction (XRD), electrochemically by cyclic voltammetry (CV), and electrochemical impedance spectroscopy (EIS). The proposed sensor displayed high electrocatalytic activity towards electro-oxidation of BPA with one irreversible peak. The fabricated sensor displayed a wide detection window between 0.025 μM and 250 μM with a limit of detection of 0.012 μM. PGE sensor was successfully engaged for the detection of BPA in bottled water, biological, and baby glass samples. 相似文献
994.
Fatima Gul Naz Paliwal Sarvesh K. Saraf Shailendra K. 《Russian Journal of General Chemistry》2021,91(2):285-293
Russian Journal of General Chemistry - A number of novel 7-chloro-4-aminoquinoline derivatives have been efficiently synthesized by nucleophilic aromatic substitution reaction of... 相似文献
995.
Nipruk O. V. Klinshova K. A. Chernorukov G. N. Bakhmetev M. O. Nazmutdinov M. D. 《Russian Journal of General Chemistry》2021,91(3):440-444
Russian Journal of General Chemistry - Cesium uranate [Cs2(Н2О)3][(UO2)6O3(OH)8]·2H2O was obtained by reacting hydrated uranium(VI) oxide UO3·2.25H2O with a cesium nitrate... 相似文献
996.
Kumar A. Kishore Sunitha V. Ramesh G. Jeshma K. 《Russian Journal of General Chemistry》2021,91(12):2546-2553
Russian Journal of General Chemistry - A series of novel 1,2,3-triazoles (8a–8m) were synthesized using click chemistry in excellent yields and were characterized by IR, NMR, MASS... 相似文献
997.
Petrosyants S. P. Babeshkin K. A. Ilyukhin A. B. Efimov N. N. 《Russian Journal of Coordination Chemistry》2021,47(3):165-173
Russian Journal of Coordination Chemistry - The complexes [Tb(Bipy)2(H2O)2Cl2]Cl (I), [Ln(Bipy)(H2O)6]Cl3·2H2O·0.5Bipy (Ln = Dy (II), Yb (IV)), [Er(Bipy)2(H2O)3Cl]Cl2·2H2O (III), and... 相似文献
998.
Rumyantsev R. V. Fukin G. K. Baranov E. V. Cherkasov A. V. Kozlova E. A. 《Russian Journal of Coordination Chemistry》2021,47(4):235-243
Russian Journal of Coordination Chemistry - The electron density distributions obtained by the quantum-chemical (density functional theory) calculations and molecular invariom model in the trimeric... 相似文献
999.
Zaitsev K. V. Oprunenko A. Yu. Gloriozov I. P. Nechaev M. S. Oprunenko Yu. F. Kuznetsov A. E. 《Russian Journal of General Chemistry》2021,91(5):828-834
Russian Journal of General Chemistry - Structures of exo- and endo-complexes of fullerene C60 with zero-valent Fe0, in which the metal is localized inside and outside fullerene molecule,... 相似文献
1000.
Sholokhova A. Yu. Shashkov M. V. Patrushev Yu. V. Matyushin D. D. Zhdanov A. A. Dolgushev P. A. Buryak A. K. 《Russian Journal of Applied Chemistry》2021,94(1):122-128
Russian Journal of Applied Chemistry - The liquid fraction of tire pyrolysis products was comprehensively analyzed by gas chromatography–mass spectrometry and two-dimensional gas... 相似文献